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Nature of the first exothermic peak on the DSC curve of linear polydicyclopentadiene obtained with a special catalytic system

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: D. Dimonie, M. Dimonie, V. Munteanu, H. Iovu, J. Couve and M.J. Abadie

Editorial: Polymer Degradation and Stability, 70(3), p.319-324, 2000.


A DSC and TGA study of linear polydicyclopentadiene (L-PDCPD) shows that the thermal behaviour of this polymer is characterized by an endothermic and two exothermic processes. In previous work it was demonstrated that the endothermic process is a glass transition and the second exotherm represents the thermo-oxidation of the polymer. In this work the first exothermic process is shown to be a possible thermal polymerization of the double bonds in the polymer chains.

Cuvinte cheie: Linear polydicyclopentadiene, Thermal polymerization, Thermo-oxidation, Crosslinking, Polyannelated structure, FTIR simulation