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Synthesis, crystal structure and photophysical properties of europium(III) and terbium(III) complexes with pyridine-2,6-dicarboxamide

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: S. Tanase, P. Marques Gallego, R. de Gelder and W. T. Fu

Editorial: Inorg. Chim. Acta, 360(1), p.102-108, 2007.


The reactions of pyridine-2,6-dicarboxamide with europium(III) and terbium(III) triflates led to the formation of mononuclear complexes of formula [Ln(pcam)3](CF3SO3)3 (Ln = Eu 1, Tb 2; pcam stands for pyridine-2,6-dicarboxamide). From single-crystal X-ray diffraction analysis, the complexes were found to be isomorphous and isostructural. The [Ln(pcam)3]3+ cations and triflate counterions are connected by intermolecular hydrogen bonds, resulting in a 3D network structure. Both the europium(III) and terbium(III) complexes exhibit efficient ligand sensitized luminescence in the visible region with lifetimes of 1.9 ms and 2.2 ms, respectively, in the solid state.

Cuvinte cheie: Lanthanide; Pyridine-2,6-dicarboxamide; Luminescence