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Spectral Investigations of Fullerene{Porphyrin Complexes

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: B. Barszcz, A. Bogucki, B. Laskowska, R.M. Ion, A. Graja

Editorial: ACTA PHYSICA POLONICA A, 112, p.143-152, 2007.

Rezumat:

Spectral investigations of some m-oxo-dimer complexes of trivalent
metals (Mn, Fe) with two di®erent ligands: tetraphenylporphyrin and
tetranaphthylporphyrin (TNP), and fullerene (C60 and C70) complexes with
m-oxobis[5,10,15,20-tetraarylporphyrinatometal (III)] (TXP-M)2O dimer,
where M = Fe, Mn and X = phenyl or naphthyl, are presented. Discus-
sion of the main electronic and vibrational bands observed in the UV-Vis-IR
and Raman spectra of both classes of fullerene{porphyrin systems is given.
Experimental data are completed with the quantum chemical calculations of
MnTNP+ component.

Cuvinte cheie: porfirine, fulerene // porphyrins, fullerenes