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Thermodynamic properties of binary pentan-3-one + chloroalkane mixtures

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: Teodorescu M.

Editorial: CHISA'98, 13th International Congress of Chemical and Process Engineering, 23-28 August, Prague (Czech Republic), Proceeding on CD-ROM, E.3.1, No. index 280, p.1-15, 1998.

Rezumat:

In the frame of a project dealing with phase equilibria in ketones + chloroalkanes, isothermal vapour-liquid equilibrium P-x-y data are reported for binary mixtures containing pentan-3-one with 1,2-dichloroethane (from 323.15 to 353.15 K), 1,3-dichloropropane (from 343.15 to 373.15 K), 1,4-dichlorobutane (from 343.15 to 373.15 K), trichloromethane (from 313.15 to 343.15 K), 1,1,1-trichloroethane (from 323.15 to 353.15 K), and 1,1,2,2-tetrachloroethane (from 343.15 to 373.15 K). In order to complement the data on VLE, and to investigate the influence of molecular structure of these chloroalkanes in their mixtures with pentan-3-one, molar excess volume, VE, obtained from the density measurements at 298.15 K and atmospheric pressure, over the whole composition range are presented. The VLE and VE experimental data are correlated by means of the Redlich-Kister equation using the maximum likelihood procedure.

Cuvinte cheie: VLE, densities, excess volumes, pentan-3-one, chloroalkanes, experimental data, correlation, Redlich-Kister, maximum likelihood procedure