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Dioxovanadium(V) complexes with side chain substituted N-salicylidenehydrazides: modelling supramolecular interactions in vanadium haloperoxidases

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: A. Pohlmann, S. Nica, W. Plass

Editorial: Inorg. Chem. Commun. , 8, p.289-292, 2005.

Rezumat:

The water soluble ammonium salts of cis-dioxovanadium(v) complexes with side chain functionalized N-salicylidenehydrazides show hydrogen bonding interactions relevant for haloperoxidase enzymes. Under turnover conditions for the catalytic bromination of trimethoxybenzene, no substitution of the side chain hydroxy group is observed.

Cuvinte cheie: haloperoxidaze, Complex vanadiu, N-salicilidenhidrazide, Structura cristalina, Interactii prin legaturi de hidrogen // Haloperoxidases, Vanadium complex, N-Salicylidenehydrazides, Crystal structure, Hydrogen bonding interaction