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Cycloheptanic sugar mimetics, bridging the gap in the homologous series of carbocyclic analogues

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: E. Sisu, M.Sollogoub J.M.Mallet, P.Sinay

Editorial: Elsevier, Tetrahedron, 58, p.10189-196, 2002.

Rezumat:

The cycloheptanic analogues of a-D-glucopyranose and b-D-mannopyranose have been synthesized. These two members of a
new class of carbocyclic sugar mimetics are filling the gap between already existing cyclohexanic and cyclooctanic classes of sugar
mimetics.

Cuvinte cheie: carbohidrati,carbazaharuri,cicloheptani,transpozitie Claisen, Triizobutil aluminiu // carbohydrates; carbasugars; cycloheptanes; Claisen rearrangement; triisobutylaluminium.