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Co(II)-Ni(II) heteropolynuclear coordination compound obtained through the reaction of 1,2-propanediol with metallic nitrates as precursor for mixed oxide of spinel type NiCo2O4

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: Niculescu, M., Birzescu, M., Dumitru, R., Sisu, E., Budrugeac, P.

Editorial: Elsevier, Thermochim.Acta, 493, p.1-5, 2009.

Rezumat:

In this paper the authors present the experimental results of the thermal analysis of heteropolynuclear
coordination compound [Co2NiL3(OH)3(H2O)3]n, where L is lactate anion, obtained by a new method,
through the reaction of 1,2-propanediol with M(NO3)2·6H2O (M: Co, Ni).
The reaction between 1,2-propanediol and M(NO3)2·6H2O (M: Co, Ni) occurs with the oxidation of
1,2-propanediol to the lactate anion (L), coordinated to M(II).
The thermal properties of the synthesized polynuclear coordinationcompound, [Co2NiL3(OH)3(H2O)3]n,
have been investigated by TG, DTG and DTA.
The mixed oxide of spinel type, NiCo2O4, impurified with NiO, obtained by thermal decomposition of
heteropolynuclear coordination compound was characterized by IR spectroscopy, X-ray powder diffraction
(XRD) and elemental analysis.

Cuvinte cheie: Analiza termica, spinel, 1,2-propandiol // Precursor 1,2-Propanediol Lactate Thermal analysis Spinel