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Isothermal Vapour+Liquid Equilibrium and Thermophysical Properties for 1-Butyl-3-methylimidazolium Chloride + 1-Butanol Binary System

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: Teodorescu M.

Editorial: Rev. Chim (Bucharest), 66 (4), p.529-536, 2015.

Rezumat:

Experimental isothermal vapour+liquid equilibrium (VLE) data are reported for the binary mixture containing 1-butyl-3-methylimidazolium chloride ([bmim]Cl) + 1-butanol at three temperatures: (353.15, 363.15, 373.15) K, in the range of 0-0.17 liquid mole fraction of [bmim]Cl. Additionally, refractive index measurements have been performed at three temperatures: (298.15, 308.15 and 318.15) K in the whole composition range. Densities, excess molar volumes, surface tensions and surface tension deviations of the binary mixture were predicted by Lorenz-Lorentz (nD-rho) mixing rule as well as dielectric permittivities and their deviations by known equations. Both types of experimental data were correlated using the Redlich-Kister models by means of maximum likelihood method

Cuvinte cheie: Low pressure VLE, refractive index, 1-butyl-3-methylimidazolium chloride ([bmim]Cl), 1-butanol