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Articolele autorului Radu CustelceanLink la profilul stiintific al lui Radu Custelcean
Supramolecular Synthesis through Dihydrogen Bonds: Self-Assembly of Controlled Architectures from NaBH4-Poly(2-hydroxyethyl)cyclen Building Blocks
A systematic investigation of molecular structures/supramolecular organizations relationships in dihydrogen-bonded complexes comprising NaBH4 and poly-2-hydroxyethyl-cyclen (poly-HEC) building blocks is reported. Like in the prototype compound 1, a (NaBH4-poly-HEC)2 dimeric arrangement has been found in the analogous structures 3 and 5, but not in compound 2, which lacks dihydrogen bonds. The exact connectivity of the dimers is determined by a complex
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