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Distinguishing between Abstraction and addition as the First step in the Reaction of a Nitroxyl Radical with Cyclohexene

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: Sergiu Coseri and Keith Ingold

Editorial: Organic Letters, 6 (10), p.1641-1643, 2004.

Rezumat:

An unambiguous method for distinguishing between abstraction-addition and addition-abstraction mechanisms (and mixtures thereof) in the reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl with a specifically deuterated cyclohexene, 1,2-dideuterocyclohexene, is demonstrated

Cuvinte cheie: cyclohexene reactions, radicals, reaction mechahism