Inscriere cercetatori

Site nou !

Daca nu va puteti recupera parola (sau aveti alte probleme), scrieti-ne la pagina de contact. Situl vechi se gaseste la adresa old.ad-astra.ro

Facebook

Cyanide-Bridged Fe(III)-Mn(III) Chain with Metamagnetic Properties and

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: S.Wang, M. Ferbinteanu, M. Yamashita

Editorial: Inorganic Chemistry, 46, p.610-612, 2007.

Rezumat:

The assembling of [Mn(5-MeOsalen)(H2O)]and [(Tp)Fe(CN)3]-affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)‚2CH3OH]n , Tp- hydrotris(pyrazolyl)borate and
5-MeOsalen2- N, N-ethylenebis(5-methoxysalicylideneiminate)].The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.

Cuvinte cheie: metamagnetism, ab-initio calculation