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Long-Range Magnetic Ordering in a TbIII-MoV Cyanido-Bridged Quasi-One-Dimensional Complex

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: F. Prins, E. Pasca, L. J. de Jongh, H. Kooijman, A. L. Spek, S. Tanase

Editorial: Angew. Chem. Int. Ed., 46(32), p.6081-6084, 2007.

Rezumat:

The new one-dimensional polymer [Tb(pzam)3(H2O)Mo(CN)8]•H2O has been synthesized and characterized; magnetic susceptibility data indicate a substantial ferromagnetic superexchange between Tb(III) and Mo(V) via the cyanido bridge, and the occurrence of long- range magnetic ordering between chains at Tc ≈ 1 K.

Cuvinte cheie: heterometallic complexes • lanthanides • magnetic properties • molybdenum • N,O ligands