Autori: TÜNDE JURCA*, ELEONORA MARIAN, FLORIN BANICA

Editorial: Revista de chimie, 61, nr.5, p.4, 2010.

Rezumat:

In this paper we report the synthesis of a series of transitions metal complexes with guanfacine (GUAF):
[Cu(GUAF)2](C6H5COO)2, [Cd(GUAF)2](C6H5COO)2. The given formula was confirmed by elemental analysis.
Spectroscopic studies including FT-IR, FT-Raman and EPR spectroscopy were performed in order to establish
the conformational and structural changes due to the complexation. Comparison between the FT-IR and FTRaman
spectra of the ligands and the corresponding complexes allowed to predict the coordination geometry.
The complexes appear to be tetradentate coordinated and metal to ligand molar ratio is found to be 1:2 for
all the compounds

Cuvinte cheie: Guanfacine, FT-IR, Raman, metal complexes

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