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Some Aspects of the Thermal Stability of Linear Polydicyclopentadiene(L-PDCPD)

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: D. Dimonie, M. Dimonie, S. Stoica, V. Munteanu and M.J. Abadie

Editorial: Polymer Degradation and Stability, 67(1), p.167-170, 2000.


L-PDCPD, obtained with catalysts based on a tungsten complex and allylsilanes has good thermal stability. TGA measurements, in air, show that the first weight losses begin around 350°C. The influence of cocatalyst, macromolecular chain defects, and fast electrons irradiation on the thermal stability of L-PDCPD is presented. The thermal stability of L-PDCPD depends to a certain extent on the type of cocatalysts used in polymerization. Branching of L-PDCPD significantly decreases the thermal stability of polymer. Irradiation with small doses of fast electrons does not essentially affect the thermal behaviour of L-PDCPD.

Cuvinte cheie: L-PDCPD, polymer thermal stability, electron beams