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New bis Aromatic Diazenes Containing Azulene-1-yl Moiety. II. New bis Aromatic Diazenes Containing Two Azulen-1-yl Moieties. Synthesis, Product Characterization, Electronic, NMR Spectra and Basicity

Domenii publicaţii > Chimie + Tipuri publicaţii > Articol în revistã ştiinţificã

Autori: Alexandru C. Razus, Liviu Birzan, Mihaela Cristea, Bogdan Popa

Editorial: Dyes & Pigments, 82, p.216-25, 2009.


Our study of bis-azo dyes containing azulen-1-yl moiety was continued by the investigation of bis aromatic diazenes which posses two either identical or different azulene-1-yl groups substituted in either 1,3 or 1,4-positions in bridging phenylene moiety. The syntheses occurred in good yields via diazotization of the 3- or 4-azulen-1-ylazo-phenylamines followed by coupling with azulene in a buffered medium. The electronic spectra of the synthesized compounds were analyzed by comparison with those of previously published compounds. The isosbestic points obtained by protonation of the compounds 8 and 9 enabled their pKa values to be determined.

Cuvinte cheie: azulene, azo, diazene, electronic spectra basicity