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Autori: Claude F. Leibovici and Dan Vladimir Nichita
Editorial: Springer, Chemical Papers, 64 (1), p.106-113, 2010.
This paper presents some unexpected features related to the solution of equations containing a high-order derivative of pressure with respect to volume equated to zero. For pure components, such equations define, in the pressure-temperature plane, nodal curves similar in shape to mixture spinodal curves. The analysis was made for a general form of two-parameter cubic equations of state and various numerical aspects for the Redlich-Kwong equation of state are exemplified.
Cuvinte cheie: cubic equations of state - high order derivatives of pressure with respect to volume - geometric locus - nodal curves