Calixarene transportori in membrane lichide. II. Azoderivati ai calix[4]arenei
When a chromophoric group is introduced into the appropriate position in calix[4]arenes one may expect novel association and spectral properties.This paper describes the synthesis of two "chcomophoric calixarenes" by coupling reactions between calix[4]arene and diazonium salts corresponding to 4 amino benzo 15-crown-5 and sulphanilic acid. Coupling reactions were carried out in heterogeneous medium in order to diminishing the rate of coupling and
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