PM3 Conformational analysis of the (3S,5R,6R) acetylamidopenicillanic acid.2.Electronic properties
A conformational analysis with the semiempirical PM3 method was performed for the (3S,5R,6R)-6-acetylamidopenicillanic acid. 47 distinct conformers were found within 11.36 kcal/mol. Dependence of some electronic properties of these conformers (HOMO and LUMO energies, dipole moment, νmin frequence of the minimum vibration, νMAX frequence of the maximum vibration, zero point vibration energy (ZPVE) and charge densities on atoms S1, N4, N14, O8, O12,
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