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Publicatii proprii

Polyaniline rod-like structure as self-electrocatalyst for hydrogen oxydation reactions

A chemical route for the aniline polymerization was performed in order to develop the morphology for rod-like polyaniline powder. The purpose of our research is to obtain a conductive and stable polymer, with a high surface area. The research interest is to implement the polyaniline as conducting polymers in the fuel cell technology, as self catalyst and support for noble metal deposition. The SEM micrograph shows a specific rod-like polymer morphology.

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Electrochemical deposition of polianiline thin films on carbonic substrates for utilization as hydrogen mediator and self catalyst in fuel cells

Experiments regarding the electro deposition and the characterization of polyaniline (PANI) films on Toray Graphite Paper TGPH - 090 type based carbonic substrate, via Cyclic Voltammetry are presented. The CVs at different scanning rates show a complex stepped mechanism of PANI electro-polymerization. At a fixed scanning rate of 20mV/s, the deposited film weight increases proportional with number of cycles at a rate of 1mg/(cm2 cycle), which is in

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The morphology controll of polyaniline as conducting polymer in fuel cell technology

Electrically conducting polymers described as a new class of 'synthetic metals' reached a high interest in the last years,confirmed by the 2000 Nobel Prize in chemistry for the discovery and development of conductive polymers (Alan J. Heeger, Alan G. MacDiarmid and Hideki Shirakawa). The most commonly studied classes of conducting polymer were: polyacetylene, polytiophene, polypyrole, polyaniline and derivates, being investigated as conducting matrices

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Grafting of softwood kraft pulps fibers with fatty acids under cold plasma conditions

Cold plasma treatment is used to modify the cellulosic fibers for a variety of applications. The grafting of softwood unbleached (UBP) and bleached (BP) Kraft pulp fibers has been performed under the action of cold plasma discharges, using different kinds of fatty acids. The grafted samples are characterized by FTIR spectroscopy, X-Ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), termogravimetry

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Melting behaviour of polytetra hydrofuran / cholesteryl palmitate blends investigated by two- dimensional infrared correlation spectroscopy

The melting behaviour and miscibility of the PTHF/CP blends, was investigated by FT-IR and generalized two-dimensional infrared (2D IR) correlation spectroscopy. Temperature-dependent spectral variations during the melting process in the C–H stretching (3100–2600 cm−1), C=O stretching (1800–1600 cm−1), and C–O–C stretching (1330–900 cm−1) bands regions were monitored. In the crystalline state, where the molecules form an ordered

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Two-dimensional infrared correlation spectroscopic studies of polymer blends – Specific interactions in polyetylene adipate/cholesteryl palmitate blends

Generalized two-dimensional infrared (2D IR) correlation spectroscopy has been applied to the study of the conformational changes and specific interactions in blends of polyethylene adipate (PEA) and cholesteryl palmitate (CP). IR spectra of CP, PEA, and their blends of different compositions: 10/90, 16/84, 32/68, 64/36, and 80/20 have been recorded. In order to apply 2D IR correlation analysis, the samples are divided into two sets for 2D: set A

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Structural analysis of some soluble elastins by means of FT-IR and 2D IR correlation spectroscopy

Fourier transform infrared (FT-IR) spectroscopy combined with 2D correlation spectroscopy has been used to offer some information about stability and structure of some soluble elastins. Temperature has been chosen as the perturbation to monitor the infrared behavior of various soluble elastins, namely, α- elastin p, α- elastin and k-elastin. In the 3800–2700 cm-1 region, the H-containing groups were analyzed. The bonded hydroxyls are found to

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Characterization by Fourier Transform Infrared Spectroscopy (FT-IR) and 2D IR Correlation Spectroscopy of PAMAM Dendrimer

FT-IR and 2D correlation spectroscopy were employed to study the microstructural changes ocurring during phase transitions of a liquid crystal poly(amidoamine) codendrimer (PAMAM (L1)16(L2)16) generation 3, functionalized on the terminal groups by one-chain promesogenic calamitic units (4-(4'-decyloxybenzoyloxy)- salicylaldehyde (L1)) and two-chain promesogenic calamitic units (4-(3',4'-didecyloxybenzoyloxy)salicylaldehyde (L2)). Spectral modifications

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Polymer – Coated Ferrite Nanocomposites Synthesized by Plasma Polymerization

Magnetic nanocomposites are an important class of advanced functional materials on the basis of a magnetic material and a matrix. To achieve unique mechanical, physical, chemical, and biomedical properties, one must be able to tailor only the surface structures of a nanoparticle. This requires the deposition of ultrathin and uniform films using the possibility offered by cold-plasma polymerisation process. The paper presents the synthesis of a magnetic

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Microscopical Study of Poly(Ethylene-Adipate)/Cholesteryl Palmitate Blends

Optical microscopy in ordinary and polarized light and FT-IR spectroscopy have been used to study morphology and crystalline transition of the poly(ethylene-adipate)/ cholesteryl palmitate blends. A smectic 1 to smectic 2 transition of the liquid crystalline component has been detected only in the blends, proving influence of the poly(ethylene-adipate) on the crystallization behavior of the cholesteryl palmitate.

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