Structure and some properties of new formes of tris-(2-aminoethanolato-o,n) cobalt (III)
Crystal forms of cobalt(III) tris(2-aminoethanolate) hydrates, i.e., red cubic crystals of the compo- sition fac-[Co(NH2CH2CH2O)3] 5.44H2O (fac-I 5.44H2O) and blue prismatic crystals of the composition mer- [Co(NH2CH2CH2O)3] 3H2O (mer-I 3H2O) were studied by the 59Co, 13C NMR and X-ray diffraction meth- ods. It was found that mer-[Co(NH2CH2CH2O)3] 3H2O (mer-I 3H2O) is a new pseudopolymorphic modifica- tion of fac-[Co(NH2CH2CH2O)3] 3H2O (fac-I 3H2O),
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